Mass Spectrometry of Polymers

Recent advances in soft ionization techniques for mass spectrometry of polymeric materials make it possible to determine the mass of intact molecular ions exceeding 1 × 106 Da. Developments in high-resolution mass spectrometers have additionally led to impressive advances in our ability to characterize polymers. The entire molecular mass distribution of a polymer sample can be accurately measured. From the molecular mass, the molecular formulae and information regarding polymer composition and end-groups can be deduced.

  • Pyrolysis
  • Laser desorption mass spectrometry
  • Glow Discharge Mass Spectrometry
  • MALDI
  • Liquid Chromatography- Mass Spectrometry
  • Gas Chromatography- Mass Spectrometry

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